Alcohols
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Aldehydes, Ketones

There are three classes of alcohols:

Class Formula
primary RCH2OH
secondary R1CHOHR2
tertiary R1R2R3COH

Naming: Alcohols can be named either using a name for the hydrocarbon group followed by the ending 'anol' or by naming the hydroxy group (OH group) together with its position of attachment:

Formula Preferred Name Other Possible Name
CH3CH2CH2OH n-propanol 1-hydroxypropane

Forming Alcohols:

Reactions of halides with hydroxide ion:

Reduction of acids, ketones, and aldehydes:

Hydrolysis of esters:

Reactions of Alcohols:

A primary alcohol can be oxidized to an aldehyde or a carboxylic acid:

  RCH2OH --> RCHO --> RCOOH

A secondary alcohol can be oxidized to a ketone:

  R1CHOHR2 --> R1COR2

An alcohol can react with a carboxylic acid to form an ester:

  R1OH + R2COOH --> R2COOR1

About alcohols (from chemguide, Jim Clark© 2006). An alcohol contains an -OH group. Water would be the simplest alcohol -- except that it is not organic (and, therefore, not an alcohol). Generally speaking, alcohols are expected to mix well together. Mixing with water is another matter. Methanol and ethanol mix with water in all proportions (they are miscible in all proportions). As the hydrocarbon chains become longer, the solubility changes. Generally speaking, an alcohol is less water soluble the longer its hydrocarbon chain. By the same token, the longer the chain, the more surface active an alcohol is likely to be.

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