Buffers
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A buffer [local] is a mixture of an acid with its conjugate base. Occasionally a salt such as NH4C2H3O2 acts as a buffer; the ammonium cation is a weak acid, and the acetate anion is a weak base. The resulting solution resists a change in pH.

In the case of a weak acid with its conjugate base, an addition of acid will be partly offset by reaction with the conjugate base; the addition of a base is offset as the result of reaction with the acid. Buffers are least affected by addition of acid or base (that is, they change pH least) when the acid and its conjugate base are in equal concentration. This special case arises at the half-equivalence point during titration.

Some buffer problems may require equilibrium expressions without approximations. The quadratic equation can be utilized effectively with the solver function.

The tutorial entitled Buffers-Composition is about the relative amounts of acid and salt in a buffer. The tutorial entitled Buffers-Properties is about determining the pH of a known buffer after adding an acid or a base. You have to supply the Ka table. Values in Ka tables often do not match.

Questions that will allow you to determine the composition of a buffer.

Quiz 1M Quiz 2M Quiz 3S Quiz 4S Quiz 5S
Quiz 6S Quiz 7M
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