To predict the outcome of a Bronsted-Lowry reaction requires information about the equilibrium constants (a Table of the Kas) for each acid. Listed below are two entries showing the acid and its conjugate base. The acid having the larger Ka is a stronger acid.
Here are four scenarios.
1. H2SO3 + H2C2O4 --> No reaction since both are acidic.
2. SO42- + CO32- --> No reaction since both are basic.
In a Bronsted-Lowry reaction, there is an acid on the left or reactant side competing with an acid on the right or product side. The stronger acid will cause a shift to the opposite of the equation. Suppose there are two competing acids HCO3- and HSO4-. HSO4- is the stronger acid and sets up the two following possibilities.
3. SO42- + HCO3- --> HSO4- + CO32- Reaction is not favored, since the HSO4- is the stronger acid than HCO3-.
4. HSO4- + CO32- --> SO42- + HCO3- Reaction is favored, since HSO4- is a stronger acid than the HCO3-, the acid on the product side.
The fourth scenario works owing to the fact that it has a large Keq. This is the result of the Ka for the dissociation of HSO4- being multiplied by the reverse of Ka for the dissociation for HCO3-. Recall that the Kreverse is the reciprocal of the Kforward, or Kr =1/Kf. The Kr = 1/(5.6x10-11). Examine the addition of the forward reaction of HSO4- and the reverse reaction of CO32-. Recall that K2 = 1/Ka for HCO3-. The product of K1 x K2 = Keq. In this case, the Keq is large and products are favored.